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Technical Presentations at the July 2004 Meeting 2.1
‘Predicting the Effectiveness of Corrosion
Control Measures Using Computer Simulation’,
Robert A. Adey and Ernesto Santana Diaz (BEASY) The BEASY Group was formed in 1978, and has its
Headquarters in Southampton, and in Billerica Massachusetts USA. Its main activities are Software, Publishing, Training, and
Research & Development, covering Maritime CP Systems Design, Signature
Management and Oil & Gas CP Systems Design. Modelling is used to cover the following areas:
The
advantages of computational modelling include: ·
Ease of model manipulation
for addition or movement of anodes
Physical
scale modelling can be an expensive and extremely time consuming method to
evaluate multiple ICCP system designs.
Computational modelling on the other hand is well suited for the
quick evaluation of multiple ICCP system designs once the hull geometry
has been defined. Conversely
the accuracy of computational modelling is dependent on accurate
characterizations of polarization response. Computer simulation is useful
for:
Computer
modelling provides a powerful technique for obtaining the answers required
by corrosion engineers. Will the design achieve the desired
results? In
the design process, especially for high value projects and complex
systems, prediction and simulation are essential.
The influence of design parameters as well as environments can be
simulated in computer models. 2.2
‘Methods of Surface Preparation to Extend Coating Life’,
Malcolm Morris & Graham Boaler (Leigh’s Paints) The development of modern anticorrosion coatings is governed by a number of constraints, including : - ·
Reduction of VOC's (Volatile Organic Compounds) emitted into the
atmosphere. ·
Health and safety considerations of raw materials which may affect
the manufacture, application and removal of the coating. ·
Reduction of application costs by using fewer coats to achieve
required film thickness. ·
Requirement to increase the life of the system to first
maintenance. The aim of
surface preparation is to remove any surface contamination such as millscale,
corrosion products, old coatings, grease & detritus and salt contamination,
thereby presenting a clean (and ideally profiled) surface on which to apply the
paint system. The principal methods of surface preparation are :- ·
Mechanical preparation using hand or power tools. These methods
are the most basic, but least efficient means of preparation, however factors
such as access, prohibition of blasting or simply cost may dictate their use. ·
Dry abrasive blasting using a variety of abrasive types (eg grit,
shot, sand, garnet etc). The most common method in use today; dry blasting
offers efficient removal of contaminants to present a good profiled surface
appropriate to the paint specification. Drawbacks include noise, removal of
spent abrasive, requirements for containment on site ·
Use of water as a blast medium is increasing, either as wet
abrasive slurry blasting, or ultra high pressure (UHP) water jetting, at
pressures exceeding 25 thousand psi. UHP offers very efficient removal of
contaminants, especially water soluble salts, however it will not create a
profile in steel although it will reveal any previously created profile. UHP is
considerably slower than dry blasting. ·
Flame cleaning & acid pickling - Older style methods, but
still used in specific instances. Chemical strippers can be useful for small
areas where blasting is impractical A number of
research projects were outlined, including :- Application
of an epoxy mastic / Polyurethane finish applied over millscale, dry gritblast,
UHP (with & without flash rusting) & mechanical preparation.
Results on accelerated testing showed far superior performance of dry
blast and UHP compared to mechanical preparation and smooth millscale. Similarly,
a range of coatings applied onto highly corroded scrap ballast tank steel, and
subjected to a cyclic immersion / dry test for 3 years, demonstrated that dry
blast outperforms mechanical preparation ,and this performance is further
enhanced by the use of UHP, even when light flash rusting is encountered. Use of
chemical strippers can produce a very clean surface which gives equivalent
performance on accelerated testing compared to fresh gritblast. In
conclusion, notwithstanding the introduction of sophisticated technology which
allows the performance goals of an anticorrosion paint specification to be
achieved; the foundation of any paint system is governed by the methods and
standard of surface preparation, which should be given utmost priority at the
design and execution stages of any project. "To
fail to prepare is to prepare to fail".. (anon) 4.1 ‘Demands
and expectations to protective coating systems: FPSOs versus Merchant Vessels, a
few critical differences’, Kjell Haugland (Jotun Paints, Europe, Ltd) While both merchant vessels and FPSO’s may be designed for an operating life of 20 – 25 years, the most crucial difference is the facilities and opportunities for repair and maintenance work to be carried out during this period. Merchant vessels will visit ship repair yards at regular intervals (2 – 5 years) for routine inspections and dockings, while FPSO’s are not expected to be moved from their offshore position until production from their oil field comes to an end. There will thus be distinctly different expectations to the life span and planned maintenance of the protective coating system for the two types of constructions. In
order to meet the expectations related to FPSO’s, it is imperative that the
construction yard has the capabilities and experience in working to the (often
considerably) higher standards demanded by the offshore industry, as compared to
merchant vessels. NORSOK Standard M501 is increasingly referred to for
protective coating systems on offshore projects, requiring pre-qualification of
coating material, operators, inspectors and work procedures. An ISO standard is
now being developed based on this NORSOK standard. Two
published reports, “OLF FPSO Project 2002” by The Norwegian Oil Industry
Association (www.olf.no/lesson/info/?12649)
and “FPSO Inspection Repair & Maintenance Report” (2003) by The UK
Offshore Operators Association (www.ukooa.co.uk/issues/fpso),
give critical comments to design, standard of paintwork, strategy for examining
tanks, etc. The following quote is quite representative: “Anecdotal evidence
indicates that normal shipyard standards of preparation and application will not
ensure adequate lifetime performance in such a production-critical and
structurally critical area.” Life
Cycle Cost (LCC) evaluation is a tool that can be employed to compare
alternative corrosion protection systems, in order to identify the most
economical and beneficial solution. The external hull of an FPSO requires not only protection against corrosion, but also against marine fouling. This poses quite a challenge. Since the hull is not propelled through the seas, it will appear an attractive object for marine organisms to settle on. Consequences of heavy fouling on an offshore structure include increased drag, increased weight, heavier load on the structure, increased strain on mooring facilities, possible damage to anticorrosive coating. Fouling around the British Isles can accumulate an additional weight of up to 40 kg per sq.m on unprotected surfaces. Barnacles have been observed to penetrate / lift coal tar epoxy based anticorrosive primers. Corrosion protection should be provided by a high quality epoxy or polyester based coating, possibly reinforced by glass-flakes. Fouling protection for the entire service life of an FPSO without any intermediate docking is a challenge that at this point in time has not been resolved. The best alternative is hydrolysing self-polishing antifouling paints, currently applied in thickness to last for up to ten years. The largest
areas to be protected against corrosion in FPSO’s are in tanks. Limited
resources and facilities combined with operational restrictions make maintenance
work in these areas very difficult. Needless to say, the initial coating system
must be of the highest quality both for materials and workmanship. Corrosion in
tanks starts predominantly in areas with low film thickness and/or poor surface
preparation. Special attention must be given to sharp edges, inside &
outside corners, rough welds, and areas difficult to reach (e.g. shadow-side of
angle-bars), etc. After steel preparation a stripe-coat must be applied before
each full coat in these areas. Osmotic
blistering will occur when paint has been applied on a surface contaminated by
water-soluble salts. Sea salt is readily available offshore, but also welding
smoke is soluble in water and will create osmotic blistering. Salt
concentrations on a substrate can be measured relatively quickly (Bressle
method). Fresh water cleaning is the only effective method for removal of
soluble salts, solvent cleaning, blast cleaning, wire brushing, etc. is not good
enough. Availability of fresh water may be restricted offshore. A
similar effect to osmosis, called Cold Wall Effect, may take place when there is
a certain temperature gradient across the paint film. A driving, permeating
force will assist ionic passage through a coating to a metal in the direction
from hot liquid to a cold wall. This effect is often seen on the coated interior
surfaces of tanks containing warm water, when the exterior side is noticeably
colder (i.e. not insulated). Given time, even relatively small temperature
differentials may produce cold wall blistering. It is most often eliminated by
proper tank or pipe insulation. This may also occur on non-immersed coatings,
e.g. externally on tanks containing cold water or fuel, when the external air is
warm and humid (forming condensation). Microbiologically
Influenced Corrosion (MIC) is in this environment most often caused by Sulphate
Reducing Bacteria (SRB). They may develop at the bottom of tanks under mud or
slime (require oxygen-free conditions). SRB reduce sulphate to sulphide, which
shows up as black ferrous sulphide when iron is available. The lower / bottom
plates in tanks are the most vulnerable areas. A new
variety of a well-proven ballast tank coating contains an optically active
ingredient that lights up under UV-light. When the first coat containing the
optically active additive is inspected under UV-light, any defect in the coating
can easily be identified and rectified before the next coat is applied. The
second coat does not contain the special additive. When this coat is inspected
under UV-light, any defects in the film will show up as illuminated areas /
spots by the first coat “shining through” the second coat. Pinholes,
holidays, low film thickness, cracks, poorly covered edges, etc. can be
identified easily and repaired for each coat. Photographs can be taken for
records. Ballast
tanks should be protected by a bespoke ballast tank coating (utilise new optical
QC technology). In cargo tanks at least the lower and upper areas should be
protected by a good quality high-build epoxy or vinyl-ester based coating (may
be reinforced by glass flakes). Slop tanks must be protected throughout by a
good quality high-build epoxy or vinyl-ester based coating (may be reinforced by
glass flakes). CONCLUSION
The objectives of ICCP were considered with reference to maintenance of structure potential, comparison with sacrificial systems, and whether corrosion was eliminated. Types of ICCP equipment were described, with their characteristics:
System Geometry: the importance of good layout was discussed, as were the uses of Computer Modeling and Physical Scale Modeling. Where next? The future of ICCP will involve the increased use of Condition-based Maintenance and ICCP of Enclosed Spaces. |